The aims of this cruise were to elucidate the processes responsible for controlling iodocarbon concentrations and provide a dataset that can be used to develop modelled estimates of iodocarbon sea-air fluxes in tropical Atlantic waters.

The cruise is a component of RAPID-WATCH, whose objectives are: to deliver a decade-long time series of calibrated and quality-controlled measurements of the Atlantic MOC from the RAPID-WATCH array and; to exploit the data from the RAPID-WATCH array and elsewhere to determine and interpret recent changes in the Atlantic MOC, assess the risk of rapid climate change, and investigate the potential for predictions of the MOC and its impacts on climate. Objectives of this cruise: to recover, calibrate and redeploy moorings from the eastern boundary and mid-Atlantic ridge subarrays of the 26.5N line of RAPID moorings.

CD170 was a collaborative cruise with the Knorr cruise KN182_2. The latter cruise was conducted between 2 May 2005 and 26 May 2005. These cruises were completed as part of the UK Natural Environment Research Council (NERC) funded RAPID Programme and the US National Science Federation (NSF) funded MOCHA Programme to monitor the Atlantic Meridional Overturning Circulation at 26.5 degrees North. The primary purpose of both cruises was to service the 26.5 degrees North mooring array deployed in 2004 during RRS Discovery cruises D277 and D278. These cruises are the first annual refurbishment of this array.

This cruise was completed as part of the United Kingdom Natural Environment Research Council (NERC) funded RAPID Programme to monitor the Atlantic Meridional Overturning Circulation at 26.5ºN. The primary purpose was to service the Eastern Boundary and Mid-Atlantic ridge sections of the 26.5ºN mooring array. The Rapid-MOC array of moorings was deployed across the Atlantic to set up a pre-operational prototype system to continuously observe the Atlantic Meridional Overturning Circulation (MOC). This array will be further refined and refurbished during subsequent years as part of the Rapid-WATCH programme. The instrumentation deployed on the array consists of a variety of CTD loggers, current meters, bottom pressure recorders, and Inverted Echo-sounders, which, combined with time series measurements of the Florida Current and wind stress estimates, can be used to determine the strength and structure of the MOC.

These mooring operations were completed as a part of the United Kingdom Natural Environment Research Council (NERC) funded RAPID Programme to monitor the Atlantic Meridional Overturning Circulation at 26.5°N. The primary purpose of this cruise was to service the Eastern Boundary and Mid-Atlantic Ridge sections of the 26.5°N mooring array first deployed during RRS Discovery cruises D277 and D278 (SOC cruise report number 53), and serviced in 2005 during RRS Charles Darwin cruise CD177 (NOCS cruise report number 5), in 2006 on RRS Discovery cruise D304 (NOCS cruise report number 16) and FS Poseidon cruises P343 and P345 (NOCS cruise report number 28) and in 2007 on RRS Discovery cruise D324 (NOCS cruise report number 34). Cruise D334 started and finished in Tenerife, Spain and covered the Eastern Boundary and Mid-Atlantic Ridge moorings deployed on D324 and P343. This cruise was the fourth annual refurbishment of the Eastern Boundary and Mid-Atlantic Ridge sections of the mooring array. The array will be further refined and refurbished during subsequent years. The instruments deployed consist of a variety of current meters, bottom pressure recorders, CTD loggers and Inverted Echosounders, which, combined with time series measurements of the Florida Straits current and wind stress estimates, will be used to determine the strength and structure of the MOC at 26.5°N.

Objectives: To quantify marine halocarbon emission variability and latitudinal variation, characterise in situ open ocean atmospheric reactive iodine latitudinal variability and characterise oxidative chemistry perturbation due to oceanic emission of halogens from the Mauritanian upwelling region. Rationale: Transecting from the UK through Biscay, south past the west coast of Africa, through the Mauritanian upwelling, to pass Cape Verde simultaneous to the intensive deployment at the UK SOLAS Observatory on Sao Vicente, the measurements made on Discovery cruise D319 are intended to provide a detailed latitudinal characterisation of marine atmospheric halogen chemistry. This will feed validation and constraint data to regional and global models in projects linked to RHaMBLe. In addition the cruise will address a number of key scientific questions required to determine the global importance of iodine chemistry and to further our understanding of the controls of halogen chemistry in the remote ocean: i) How heterogeneous are the direct halogen sources and on what scale is the heterogeneity - does the upwelling region produce more or less halogens than the 'background' region? ii) What are the relative contributions of I atoms to the remote MBL from I2 and organic iodine? iii) Is sufficient iodine released to the remote MBL to sustain aerosol nucleation or to significantly affect the ozone budget and free radical populations? Measurement Description: Measured species included a variety of halocarbons in both water column and atmosphere and atmospheric boundary layer measurements of I2, OIO and IO by Broadband Cavity Enhanced Absorption Spectroscopy (BBCEAS). A compact version of the FAGE system, developed for the FAAM BAe-146, was deployed to provide measurements of IO or OH / HO2, permitting direct assessment of RHS-induced changes in the oxidising environment through the upwelling region. A range of trace gas monitors was simultaneously deployed to measure O3 and NOx. Aerosol number and size distribution measurements from 3 nm to 20 micron diameter were also made by a range of mobility (SMPS) and optical instrumentation, (OPC and FSSP). Additional aerosol measurements were provided as part of the NERC-funded ACMME project (PI Allan). Measurements of pigments in the surface waters were made by HPLC. Prevailing meteorological conditions were used to direct the cruise in terms of geographical positioning and measurement interpretation, e.g. i) exploitation of any broad flow connection between Cape Verde and the ship to interpret measurements as process studies and ii) identification of in- and out-of-plume conditions to contrast chemistry influenced and uninfluenced by emissions from the upwelling region.

The purpose of the cruise was the refurbishment of an array of moorings on the mid-Atlantic Ridge and off the Moroccan Coast at nominal latitude of 26.5°N. The moorings are part of an Atlantic-wide mooring array for monitoring the Atlantic Meridional Overturning Circulation and Heat Flux. The array is a joint UK/US programme and is known as the RAPID-WATCH/MOCHA array. The RAPID transatlantic array consists of 24 moorings of which 21 are maintained by the UK, and 20 bottom landers of which 16 are maintained by the UK. The moorings are primarily instrumented with self logging instruments measuring conductivity, temperature and pressure. Direct measurements of currents are made in the shallow and deep western boundary currents. The bottom landers are instrumented with bottom pressure recorders (also known as tide gauges), measuring the weight of water above the instrument. A sediment trap mooring NOGST was also recovered and redeployed for the Ocean Biogeochemistry and Ecosystems Group at the NOCS. CTD stations were conducted at convenient times throughout the cruise for purposes of providing pre and post deployment calibrations for mooring instrumentation and for testing mooring releases prior to deployment. Shipboard underway measurements were systematically logged, processed and calibrated, including: waves (spectra of energy and significant wave height), surface meteorology (air pressure, temperature, wind speed and direction and radiation (total incident and photosynthetically active), 6m depth sea temperatures and salinities, water depth, navigation (differential GPS measurements feeding two independent and different receivers, heading, pitch and roll from a four antenna Ashtec ADU5 receiver, gyro heading and ships speed relative to the water using an electromagnetic log). Water velocity profiles from 15m to approximately 500m depth were obtained using a ship mounted 75 kHz acoustic Doppler current profiler. Seawater samples from CTD stations and of the sea-surface were obtained for calibration and analysed on a salinometer referencing these samples against standard sea water. For velocity data (wind and currents) measured relative to the ship considerable effort was made to obtain the best possible earth-referenced velocities. Four APEX Argo floats supplied by the Met Office were deployed at pre-assigned locations, filling gaps in the network.

The three key objectives of our original proposal were to test: 1. The hypothesis that mantle upwelling and melting is focused at the centres of slow spreading ridge segments and transposed by sub-horizontal flow away from there. 2. The hypothesis that plate accretion and separation mechanisms are fundamentally different in 'magma-starved' areas. 3. Mechanisms of detachment faulting and extensional strain localisation in the lower crust and upper mantle. We proposed to achieve these objectives by detailed surveying and sampling across an extensive region of magma-poor seafloor spreading around Fifteen Twenty Fracture Zone (FTFZ), coupled with microstructural, geochemical and palaeomagnetic analyses. TOBI deep-towed sidescan and magnetic data were to be obtained both to inform the choice of sampling sites and to aid in structural, lithological and geodynamic interpretations. We spent 29 days on the Mid-Atlantic Ridge (MAR) in the vicinity of 13 to 15N. We collected multibeam ship-based bathymetry, gravity and magnetic data and TOBI sidescan, magnetic and water-column data from a total area of about 8,000 km2. We recovered samples from 47 drill and dredge stations throughout the area, in support of the objectives.