The cruise is a component of RAPID-WATCH, whose objectives are: to deliver a decade-long time series of calibrated and quality-controlled measurements of the Atlantic MOC from the RAPID-WATCH array and; to exploit the data from the RAPID-WATCH array and elsewhere to determine and interpret recent changes in the Atlantic MOC, assess the risk of rapid climate change, and investigate the potential for predictions of the MOC and its impacts on climate. Objectives of this cruise: to recover, calibrate and redeploy moorings from the eastern boundary and mid-Atlantic ridge subarrays of the 26.5N line of RAPID moorings.

Cruise D344 was primarily used for the annual servicing of the eastern boundary and mid-Atlantic ridge moorings that form part of the RAPID-MOC mooring array across the North Atlantic at 26°N. In addition, the easternmost western boundary mooring, WB6, was serviced and the trial current meter mooring off the island of Abaco, WB-CM, was recovered. As the Discovery had made a faster passage than anticipated, a number of CTD stations were performed along 24° 30'N to augment the hydrography section scheduled to take place in January 2010. The instruments deployed on the RAPID-MOC array consist of bottom pressure recorders, CTD loggers, and current meters which, combined with time series measurements of the Florida Channel Current, and wind stress estimates, will be used to determine the strength and structure of the MOC at 26.5°N.

The main testable hypothesis of the proposed work is: Atmospheric inputs control rates of primary production and microbial diversity in oceanic waters where nutrients are limiting. The objectives of the project are to: 1. Obtain an improved temporal and spatial estimate of atmospheric dust inputs to the tropical N Atlantic through collections on a dedicated SOLAS process cruise. 2. Obtain an improved estimate of the seawater dissolution of N, P, Fe and Zn species from aerosol dust. 3. Determine the impact of atmospheric dust derived micronutrients on microbial community production and species diversity in the surface microlayer and underlying waters. In addition, researchers from the Archer/Geider group were on-board. The overall aim of their research was to determine the extent to which the photoprotective roles of DMSP and QAs influence their production rates in marine surface waters and hence, the production of their volatile breakdown products. The cruise objectives for this work were to: 1. relate DMSP and QAC concentrations to plankton community structure, light regime, photoinhibition, xanthophyll cycle and MAA accumulation in varying oceanic provinces and over diel cycles. 2. determine the potential for photoinhibition and DMSP/GBT turnover in natural phytoplankton in contrasting oceanic provinces. The cruise departed Tenerife on February 5, 2008, and we have conducted regular stations (typically 2 per day) along the cruise track. The track took us into the oligotrophic Atlantic waters, productive Cape Verde waters, and tropical waters with very high nitrogen fixation (judged initially from the Trichodesmium concentrations). The various researchers and groups have also started a range of biological experiments at different sites along the cruise track. We have encountered a major dust event in week 2, and then from week 3 of the cruise we encountered large amounts of dust. We have visited the TENATSO time series site near the Cape Verdes and have undertaken an extensive set of measurements there. We have collected the atmospheric dust for elemental analyses (at UEA and NOCS), and also to produce leachates which are used on board for biological experiments. We have undertaken sampling of the water column to analyse for dissolved and particulate metals, nutrients, dissolved organic matter, amino acids, hemes, thiols and phytochelatin synthase expression. In addition, nitrogen fixation measurements were undertaken, in tandem with nifh gene sampling. Nitrate uptake experiments have been conducted. Furthermore, bacterial phosphate uptake experiments have been undertaken using addition of collected dust. Halocarbon and DMS gas measurements have been conducted during the cruise. In addition, experiments have been undertaken by the Archer/Geider group on effects of high sun light exposure on DMS and GBT production. The cruise has been very successful with a minimum of lost time.

Objectives: To quantify marine halocarbon emission variability and latitudinal variation, characterise in situ open ocean atmospheric reactive iodine latitudinal variability and characterise oxidative chemistry perturbation due to oceanic emission of halogens from the Mauritanian upwelling region. Rationale: Transecting from the UK through Biscay, south past the west coast of Africa, through the Mauritanian upwelling, to pass Cape Verde simultaneous to the intensive deployment at the UK SOLAS Observatory on Sao Vicente, the measurements made on Discovery cruise D319 are intended to provide a detailed latitudinal characterisation of marine atmospheric halogen chemistry. This will feed validation and constraint data to regional and global models in projects linked to RHaMBLe. In addition the cruise will address a number of key scientific questions required to determine the global importance of iodine chemistry and to further our understanding of the controls of halogen chemistry in the remote ocean: i) How heterogeneous are the direct halogen sources and on what scale is the heterogeneity - does the upwelling region produce more or less halogens than the 'background' region? ii) What are the relative contributions of I atoms to the remote MBL from I2 and organic iodine? iii) Is sufficient iodine released to the remote MBL to sustain aerosol nucleation or to significantly affect the ozone budget and free radical populations? Measurement Description: Measured species included a variety of halocarbons in both water column and atmosphere and atmospheric boundary layer measurements of I2, OIO and IO by Broadband Cavity Enhanced Absorption Spectroscopy (BBCEAS). A compact version of the FAGE system, developed for the FAAM BAe-146, was deployed to provide measurements of IO or OH / HO2, permitting direct assessment of RHS-induced changes in the oxidising environment through the upwelling region. A range of trace gas monitors was simultaneously deployed to measure O3 and NOx. Aerosol number and size distribution measurements from 3 nm to 20 micron diameter were also made by a range of mobility (SMPS) and optical instrumentation, (OPC and FSSP). Additional aerosol measurements were provided as part of the NERC-funded ACMME project (PI Allan). Measurements of pigments in the surface waters were made by HPLC. Prevailing meteorological conditions were used to direct the cruise in terms of geographical positioning and measurement interpretation, e.g. i) exploitation of any broad flow connection between Cape Verde and the ship to interpret measurements as process studies and ii) identification of in- and out-of-plume conditions to contrast chemistry influenced and uninfluenced by emissions from the upwelling region.

The aims of this cruise were to elucidate the processes responsible for controlling iodocarbon concentrations and provide a dataset that can be used to develop modelled estimates of iodocarbon sea-air fluxes in tropical Atlantic waters.