The objectives of the BELMER project are: - to validate the MERIS water products for Belgian coastal waters and neighbouring French, UK and Dutch waters - to provide a quantitative statement of product accuracy and recommendations for improvements in the scientific algorithms, where appropriate. In particular the problems reported by the MERIS validation and user communities of turbid water atmospheric correction, case 2 water chlorophyll retrieval, adjacency effects (straylight), moderate sunglint, spatio-temporal variability of specific inherent optical properties and bottom reflectance will be addressed. This project is funded by the "PROgramme for the Development of scientific Experiments" (PRODEX) of the European Space Agency (ESA).

SHOM cruise between Brest and Vigo

Overall objectives in the EU GO project are to assess the promising potential of seismic imaging for physical oceanography, in view of its combination of fine resolution and coverage unmatched by conventional oceanographic measurements. D318 was to provide the means of assessment by obtaining a unique, comprehensive, oceanographic and seismic dataset at the same time and place. Specific objectives for R.R.S. Discovery cruise 318a were to deploy four ADCP moorings, three adjacent temperature-logger moorings and STABLE, in an L-shape array in 750-1000m depth east of Portimao Canyon, carrying out adjacent CTD stations, deploy two OBH moorings, carry out seismic sections using the Ifremer high-frequency air-guns and streamer, accompanied by regular XBT and less frequent XCTD casts. In addition underway data was logged including ship-borne ADCP, surface temperature and salinity, meteorology, gravity and magnetics (to test new NERC magnetometers).

The overall aim of the UKSOLAS project DOGEE-SOLAS is the parameterization of air-sea gas exchange, which is a currently a major uncertainty in global modelling. RRS Discovery cruise D320 thus was primarily concerned with the measurement of air-sea gas transfer velocities and some of the important physical parameters that influence them through contributing to near surface turbulence, and other processes. In brief, specific cruise objectives were: 1. Determine open ocean gas transfer velocities through a number of dual-tracer releases (3He & SF6). 2. Investigate the role of surfactant in gas exchange through a targeted surfactant release in conjunction with (1). 3. Determine CO2 fluxes and transfer velocities, and make associated hydrographic and turbulence related measurements from autonomous ASIS (Air-Sea Interaction Spar) buoys. 4. Measure air-sea fluxes of CO2, sensible heat, latent heat and momentum using the AUTOFLUX automated sensor array 5. Measure underway, total gas tension, dissolved O2, and CO2 to obtain independent air-sea gas exchange estimates. 6. Make covariance and gas budgeting estimates of air-sea gas exchange using intelligent profiling Lagrangian floats. 7. Independently determine DMS fluxes and gas transfer velocities for comparison with CO2 to examine the role of gas solubility in gas transfer. 8. Deploy a spar buoy (NOC) for measurement of wave heights and bubble properties 9. Record and measure whitecap coverage and wave breaking coincident with the air-sea flux measurements using ship mounted cameras 10. Record key meteorological variables 11. Quantify flow distortion biases in the direct flux measurements via the use of established models. 12. Make biogas, surfactant and bacterial measurements in the surface microlayer and in the uppermost metres of the ocean using surface microlayer samplers, a remotely operated catamaran, and a near surface sampler. 13. Deploy an autonomous powered profiler (ASIP) for turbulence-related measurements in the mixed layer. Objectives 1-12 were all met. Unfortunately, due to mechanical failure and loss of ASIP, objective 13 was not realised.

The aims of this cruise were to elucidate the processes responsible for controlling iodocarbon concentrations and provide a dataset that can be used to develop modelled estimates of iodocarbon sea-air fluxes in tropical Atlantic waters.

SHOM cruise between Brest and Lisbon

Objectives: To quantify marine halocarbon emission variability and latitudinal variation, characterise in situ open ocean atmospheric reactive iodine latitudinal variability and characterise oxidative chemistry perturbation due to oceanic emission of halogens from the Mauritanian upwelling region. Rationale: Transecting from the UK through Biscay, south past the west coast of Africa, through the Mauritanian upwelling, to pass Cape Verde simultaneous to the intensive deployment at the UK SOLAS Observatory on Sao Vicente, the measurements made on Discovery cruise D319 are intended to provide a detailed latitudinal characterisation of marine atmospheric halogen chemistry. This will feed validation and constraint data to regional and global models in projects linked to RHaMBLe. In addition the cruise will address a number of key scientific questions required to determine the global importance of iodine chemistry and to further our understanding of the controls of halogen chemistry in the remote ocean: i) How heterogeneous are the direct halogen sources and on what scale is the heterogeneity - does the upwelling region produce more or less halogens than the 'background' region? ii) What are the relative contributions of I atoms to the remote MBL from I2 and organic iodine? iii) Is sufficient iodine released to the remote MBL to sustain aerosol nucleation or to significantly affect the ozone budget and free radical populations? Measurement Description: Measured species included a variety of halocarbons in both water column and atmosphere and atmospheric boundary layer measurements of I2, OIO and IO by Broadband Cavity Enhanced Absorption Spectroscopy (BBCEAS). A compact version of the FAGE system, developed for the FAAM BAe-146, was deployed to provide measurements of IO or OH / HO2, permitting direct assessment of RHS-induced changes in the oxidising environment through the upwelling region. A range of trace gas monitors was simultaneously deployed to measure O3 and NOx. Aerosol number and size distribution measurements from 3 nm to 20 micron diameter were also made by a range of mobility (SMPS) and optical instrumentation, (OPC and FSSP). Additional aerosol measurements were provided as part of the NERC-funded ACMME project (PI Allan). Measurements of pigments in the surface waters were made by HPLC. Prevailing meteorological conditions were used to direct the cruise in terms of geographical positioning and measurement interpretation, e.g. i) exploitation of any broad flow connection between Cape Verde and the ship to interpret measurements as process studies and ii) identification of in- and out-of-plume conditions to contrast chemistry influenced and uninfluenced by emissions from the upwelling region.